2018 旭硝子財団 助成研究発表会 要旨集

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DFT33.8 kcal/mol(H3PBH3)+1.650.670.820.340HOMO (3.81 eV)σ3LUMO (1.52 eV)* 3HOMO()LUMO() THF11B NMR31P NMR11B NMRTHF THF4 4 3. 54 4. [1] N. Kano, N. J. Oʼ Brien, R. Uematsu, R. Ramozzi and K. Morokuma, 2017, Angew. Chem. Int. Ed., 556(21): 5882-5885. [2] H. Miyake, N. Kano and T. Kawashima, 2009. J. Am. Chem. Soc., 1131(46): 16622-16623. 5. 171-85881-5-1 Tel: 03-5984-9393 E-mail: naokazu.kano@gakushuin.ac.jp －49－