2018 旭硝子財団 助成研究発表会 要旨集

53/198

1 Entry Solvent Pressure (atm) Flow rate (mL/min) Length (m) Result 1 PhCl 12 0.40 50 50% 2 toluene 5.0 1.0 8.0 n.d. 3 toluene 12 1.0 8.0 n.d. 4 toluene 12 0.70 8.0 2% 5 toluene 12 0.40 8.0 8% 6 toluene 12 0.10 8.0 5% 7 1,4-dioxane 12 0.40 8.0 4% 8 PhCl 12 0.40 8.0 19% 9 DMF 12 0.40 50 24% entry 3-60.40 mL/minentry 5[8]0.40 mL/minentry 5, 7-8 3 19entry 850 m50 3 3. 4. [1] Robert Franke, Detlef Selent, Armin Börner, Chem. Rev. 22012, 112, 5675-5732. [2] Bernhard Breit, Acc. Chem. Res. 22003, 36, 264-275. [3] Nozomu Sakai, Satoshi Mano, Kyoko Nozaki, Hidemasa Takaya, J. Am. Chem. Soc. 11993, 115, 7033-7034. [4] Jun-ichi Yoshida, Yusuke Takahashi, Aiichiro Nagaki, Chem. Commun. 22013, 49, 9896-9904. [5] Shinichiro Fuse, Yuto Mifune, Takashi Takahashi, Angew. Chem. Int. Ed. 22014, 53, 851-855. [6] Carl J. Mallia and Ian R. Baxendale, Org. Process Res. Dev. 22016, 20, 327-360. [7] Sivarajan Kasinathan, Samuel L. Bourne, Päivi Tolstoy, Peter Koos, Matthew O’Brien, Roderick W. Bates, Ian R. Baxendale, Steven V. Ley, Synlett 22011, 2648-2651. [8] Hisashi Masui, Eiki Honda, Sakura Niitsu, Mitsuru Shoji, Takashi Takahashi, International Journal of Organic Chemistry, 22018, 8, 135-141. 5. 245-0066601045-859-1300E-mailhisashimasui@hamayaku.ac.jp －45－