2017 旭硝子財団 助成研究発表会 要旨集

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C-H 1. Ni21--2,3,4C-H 2. C-H()5Cp*Co(III)Cp*Rh(III)Cp*Ir(III)Lewis6-7CoRhIrC-H8C-H9C-H10C-H1112Co12Cp*Co(III) NOArRNNR2OCoMeMeMeMeMe(PF6)2IIIcat. Cp*CoIIIvia β-hydroxideeliminationOHRRNR1OAcRHHhigh site selectivityXYNR1RHXYHunsymmetricalNNNNRcat. Cp*CoIIINNNNRRRcat. Cp*CoIIIhigh nucleophilicityArR(SbF6)2CoMeMeMeMeMeI+ Ag-saltIIICOICoMeMeMeMeMeLL = CH3CNIIILLcat. Cp*CoIIINNNNRNNNNRF3CSNSO2PhSO2PhF3CSNHNNR2Ocat. Cp*CoIIIArRRArNR2ONOOArArO 1 Cp*Co(III)C-H −60−発表番号　30〔中間発表〕