2017 旭硝子財団 助成研究発表会 要旨集

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(4)syn-(3)3)nBuLisyn-DME anti-(4)sp2-sp370 °CBpin(4) 3(4) (4)12,6-Me2C6H3(4)4)BpinBpinDFTBpin3 4(4)Xyl(Xyl = 2,6-Me2C6H3) ()(4)(o-tol)MgBrH-HB-B(5)5)1H-HDFTH-HBMes2 5(4) 3. (4)(4)()B-BB-AlAl-Al 4. 1) Asakawa, H.; Lee, K.-H.; Lin, Z.; Yamashita, M., Nat. Commun. 2014, 5, 4245. 2) Asakawa, H.; Lee, K.-H.; Furukawa, K.; Lin, Z.; Yamashita, M., Chem. Eur. J. 2015, 21, 4267. 3) Kojima, C.; Lee, K.-H.; Lin, Z.; Yamashita, M., J. Am. Chem. Soc. 2016, 138, 6662. 4) Katsuma, Y.; Asakawa, H.; Lee, K.-H.; Lin, Z.; Yamashita, M., Organometallics 2016, 35, 2563. 5) Tsukahara, N.; Asakawa, H.; Lee, K.-H.; Lin, Z.; Yamashita, M., J. Am. Chem. Soc. 2017, 139, 2593. 5. 464-8603makoto@oec.chembio.nagoya-u.ac.jp BBMesMesOOpinBBMes2RR'additive++R'RpinBBMes2RR'pinBBMes2pinBR'RBMes2pinBRR'BMes2syn-isomersanti-isomersNBHNPh2MesMesTwo-step synthesis offluorescent molecules(nBuLI and/or DME)−103−